Photoinduced Magnetization in Copper Otacyanomolybdate

Shin-Ichi Ohkoshi (1, 2) , Hiroko Tokoro (1) , Toshiya Hozumi (1) , Yue Zhang (1) , Kazuhito Hashimoto (1) , Corine Mathonière (3) , Isabelle Bord (3) , Guillaume Rombaut (3) , Marc Verelst (4) , Christophe Cartier Dit Moulin (5) , Françoise Villain (5)

1 Department of Applied Chemistry
2 PRESTO [JST
3 ICMCB - Institut de Chimie de la Matière Condensée de Bordeaux
4 CEMES - Centre d'élaboration de matériaux et d'études structurales
5 CIM2 - Laboratoire de Chimie Inorganique et Matériaux Moléculaires

This article describes the studies of a photomagnetic cyanide-bridged Cu-Mo bimetallic assembly, CuII2[MoIV(CN)8]·8H2O (CuII, S = 1/2; MoIV, S = 0) (1), which has an intervalence transfer (IT) band from MoIV-CN-CuII to MoV-CN-CuI around 480 nm...

Mots clés: Copper Otacyanomolybdate; magnetism

Domaines: Matériaux

Shin-Ichi Ohkoshi, Hiroko Tokoro, Toshiya Hozumi, Yue Zhang, Kazuhito Hashimoto, et al.. Photoinduced Magnetization in Copper Otacyanomolybdate. Journal of the American Chemical Society, 2006, 128 (1), pp.270 - 277. ⟨10.1021/ja0559092⟩. ⟨hal-00018458⟩