Probing the 3d Spin Momentum with X-ray Emission Spectroscopy: The Case of Molecular-Spin Transitions

Gyorgy Vanko ́ (1) , Thomas Neisius (2) , Gábor Molnár (3) , Franz Renz (4) , Szilvia Karpati (5) , Abhay Shukla (6) , Frank M. F. de Groot (7)

1 ESRF - European Synchrotron Radiation Facility
2 Université Paul Cézanne - Aix-Marseille 3
3 LCC - Laboratoire de chimie de coordination
4 Institut fur Anorganische Chemie und Analytische Chemie [Mainz]
5 Department of Nuclear Chemistry [Budapest]
6 IMPMC - Institut de minéralogie et de physique des milieux condensés
7 Department of Inorganic Chemistry and Catalysis, Utrecht UniVersity,

We report X-ray emission spectra of Fe, Fe, and Cospin-crossover compounds in their high-spin and low-spin forms. It is shown that all X-ray emission features are sensitive to the spin state. Variations of the K

Domaines: Cosmologie et astrophysique extra-galactique [astro-ph.CO]

Gyorgy Vanko ́, Thomas Neisius, Gábor Molnár, Franz Renz, Szilvia Karpati, et al.. Probing the 3d Spin Momentum with X-ray Emission Spectroscopy: The Case of Molecular-Spin Transitions. Journal of Physical Chemistry B, 2006, 110, pp.11647-11653. ⟨10.1021/jp0615961⟩. ⟨hal-00128311⟩