Synthesis and structural characterisation of TPME2 Nb (Ch3)2 (CH3 C=CCH3) and TPme2 NbC1 (CH3) (CH3 C=CCH3) : is there an intrinsic agostic interaction in alkyl complexes of the TpME2 Nb(alkyne) moiety ?

Emmanuelle Teuma (1) , Michel Etienne (2) , Bruno Donnadieu (3) , G. Sean Mcgrady (2)

1 LHFA - Laboratoire Hétérochimie Fondamentale et Appliquée
2 Department of Chemistry
3 LCC - Laboratoire de chimie de coordination

Domaines: Chimie organique

Emmanuelle Teuma, Michel Etienne, Bruno Donnadieu, G. Sean Mcgrady. Synthesis and structural characterisation of TPME2 Nb (Ch3)2 (CH3 C=CCH3) and TPme2 NbC1 (CH3) (CH3 C=CCH3) : is there an intrinsic agostic interaction in alkyl complexes of the TpME2 Nb(alkyne) moiety ?. New Journal of Chemistry, 2006, 30, pp.409-415. ⟨hal-00142682⟩