Heat- and light-induced spin transition of an iron(II) polymer containing the 1,2,4,5-tetrakis(diphenylphosphanyl)benzene ligand

Patrick Rosa (1) , Amy Debay (1) , Laurence Capes (2) , Guillaume Chastanet (1) , Azzedine Bousseksou (3) , Pascal Le Floch (4) , Jean-François Létard (1)

1 ICMCB - Institut de Chimie de la Matière Condensée de Bordeaux
2 DRECAM - Département de Recherche sur l'Etat Condensé, les Atomes et les Molécules
3 LCC - Laboratoire de chimie de coordination
4 DCPH - Laboratoire Hétéroéléments et Coordination

A new iron(II) spin-crossover compound containing a phosphane ligand has been synthesized and characterized by magnetic susceptibility, Mössbauer spectroscopy, and heat capacity and photomagnetic experiments...

Mots clés: Spin crossover; Phosphate ligands; Iron; Photomagnetism; Coordination polymers

Domaines: Matériaux

Patrick Rosa, Amy Debay, Laurence Capes, Guillaume Chastanet, Azzedine Bousseksou, et al.. Heat- and light-induced spin transition of an iron(II) polymer containing the 1,2,4,5-tetrakis(diphenylphosphanyl)benzene ligand. European Journal of Inorganic Chemistry, 2004, 15, pp.3017-3019. ⟨10.1002/ejic.200400284⟩. ⟨hal-00149745⟩