Transient palladadiphosphanylcarbenes : singlet carbenes with an "inverse" electronic configuration (p2 instead of 2) and unusual transannular metal-carbene interactions (C Pd donation and Pd C back-donation)

Heinz Gornitzka (1) , J. Vignolle (1) , G. Bertrand (1, 2) , D. Bourissou (1) , Laurent Maron (3) , Wolfgang W. Schoeller (4)

1 LHFA - Laboratoire Hétérochimie Fondamentale et Appliquée
2 Department of Chemistry [Riverside]
3 LNMO - Laboratoire de Nanophysique Magnétisme et Optoélectronique
4 Fakultät für Chemie [Universität Bielefeld]

Domaines: Chimie organique

Heinz Gornitzka, J. Vignolle, G. Bertrand, D. Bourissou, Laurent Maron, et al.. Transient palladadiphosphanylcarbenes : singlet carbenes with an "inverse" electronic configuration (p2 instead of 2) and unusual transannular metal-carbene interactions (C Pd donation and Pd C back-donation). Journal of the American Chemical Society, 2007, 129, pp.978-985. ⟨hal-00274170⟩