A bi-TTF with a bipyridine spacer: 4,4 '-bis[(3,6,7-trimethylsulfanyltetrathiafulvalen-2-yl)sulfanylmethyl]-2,2 '-bipyridine

Lakhemici Kaboub (1) , Jean-Marc Fabre (2) , Jean-Pierre Legros (3)

1 Lab Chim Mat Organ
2 ICGM ICMMM - Institut Charles Gerhardt Montpellier - Institut de Chimie Moléculaire et des Matériaux de Montpellier
3 LCC - Laboratoire de chimie de coordination

The title compound, C30H28N2S16, is a precursor to hybrid magnetic materials. The complete molecule is generated by a crystallographic inversion centre. In the crystal structure, the TTF core is not planar and adopts a chair conformation; the two C3S2 rings are folded around the S center dot center dot center dot S hinges, the dihedral angles being 17.14 (8) and 13.46 (7)degrees. There is a short S center dot center dot center dot S contact [3.4863 (14) angstrom] in the crystal structure.

Mots clés: COMPLEX

Domaines: Chemo-informatique

Lakhemici Kaboub, Jean-Marc Fabre, Jean-Pierre Legros. A bi-TTF with a bipyridine spacer: 4,4 '-bis[(3,6,7-trimethylsulfanyltetrathiafulvalen-2-yl)sulfanylmethyl]-2,2 '-bipyridine. Acta crystallographica Section E : Crystallographic communications [2015-..], 2008, 64, pp.O2484-U3725. ⟨10.1107/S1600536808039111⟩. ⟨hal-00351632⟩