Activation of aryl halides by Cu(0)/1,10-phenanthroline: Cu(0) as precursor of Cu(I) catalyst in cross-coupling reactions

Mounir Mansour (1) , Roberto Giacovazzi (1) , Armelle Ouali (2, 3) , Marc Taillefer (2) , Anny Jutand (1)

1 PASTEUR - Processus d'Activation Sélective par Transfert d'Energie Uni-électronique ou Radiatif (UMR 8640)
2 ICGM ICMMM - Institut Charles Gerhardt Montpellier - Institut de Chimie Moléculaire et des Matériaux de Montpellier
3 LCC - Laboratoire de chimie de coordination

The activation of aryl iodides and bromides by Cu(0)/1,10-phenanthroline in acetonitrile (S) generates Cu(I)(phenanthroline)S2+ which can be a catalyst for cross-coupling reactions.

Mots clés: electrochemistry; copper; catalysis

Domaines: Chimie organique

Mounir Mansour, Roberto Giacovazzi, Armelle Ouali, Marc Taillefer, Anny Jutand. Activation of aryl halides by Cu(0)/1,10-phenanthroline: Cu(0) as precursor of Cu(I) catalyst in cross-coupling reactions. Chemical Communications, 2008, pp.6051-6053. ⟨10.1039/b814364a⟩. ⟨hal-00356724⟩