Hydrogen for X-group exchange in CHX (X = Cl, Br, I , OMe, and NMe) by monomeric [1,2,4-(Me3C)3C5H2]2CeH: experimental and computational support for a carbenoid mechanism

Evan L. Werkema (1) , Richard A. Andersen (1) , Ahmed Yahia (2, 3) , Laurent Maron (2) , Odile Eisenstein (4)

1 Department of Chemistry [Berkeley]
2 LPCNO - Laboratoire de physique et chimie des nano-objets
3 ICSM - UMR 5257 - Institut de Chimie Séparative de Marcoule
4 ICGM ICMMM - Institut Charles Gerhardt Montpellier - Institut de Chimie Moléculaire et des Matériaux de Montpellier

Domaines: Chimie-Physique [physics.chem-ph]

Evan L. Werkema, Richard A. Andersen, Ahmed Yahia, Laurent Maron, Odile Eisenstein. Hydrogen for X-group exchange in CHX (X = Cl, Br, I , OMe, and NMe) by monomeric [1,2,4-(Me3C)3C5H2]2CeH: experimental and computational support for a carbenoid mechanism. Organometallics, 2009, 28, pp.3173-3185. ⟨10.1021/om9001846⟩. ⟨hal-00384982⟩