Conformational control of metallocene backbone by cyclopentadienyl ring substitution: a new concept in polyphosphane ligands evidenced by "through-space" nuclear spin-spin coupling. Application in heteroaromatics arylation by direct C-H activation

Radomyr V. Smaliy (1) , Mathieu Beaupérin (1) , Hélène Cattey (1) , Philippe Meunier (1) , Jean-Cyrille Hierso (1) , Julien Roger (2) , Henri Doucet (2) , Yannick Coppel (3)

1 ICMUB - Institut de Chimie Moléculaire de l'Université de Bourgogne [Dijon]
2 ISCR - Institut des Sciences Chimiques de Rennes
3 LCC - Laboratoire de chimie de coordination

Domaines: Chimie de coordination; Catalyse

Radomyr V. Smaliy, Mathieu Beaupérin, Hélène Cattey, Philippe Meunier, Jean-Cyrille Hierso, et al.. Conformational control of metallocene backbone by cyclopentadienyl ring substitution: a new concept in polyphosphane ligands evidenced by "through-space" nuclear spin-spin coupling. Application in heteroaromatics arylation by direct C-H activation. Organometallics, 2009, 28 (11), pp.3152-3160. ⟨10.1021/om8012162⟩. ⟨hal-00458348⟩