Can a functionalized phosphine ligand promote room temperature luminescence of the [Ru(bpy)(tpy)]2+ core?

Emilie Lebon Tailhades (1) , Stéphanie Bastin (1) , Pierre Sutra (1) , Laure Vendier (1) , Rémi E. Piau (2) , Isabelle M. Dixon (2) , Martial Boggio-Pasqua (2) , Fabienne Alary (2) , Jean-Louis Heully (2) , Alain Igau (1) , Alberto Juris

1 LCC - Laboratoire de chimie de coordination
2 Chimie des éléments d & f (LCPQ)

Unexpected room temperature luminescence is observed and rationalized by highly challenging excited state calculations for a functionalized phosphine ligand coordinated on the [Ru(bpy)(tpy)](2+) core.

Domaines: Autre

Emilie Lebon Tailhades, Stéphanie Bastin, Pierre Sutra, Laure Vendier, Rémi E. Piau, et al.. Can a functionalized phosphine ligand promote room temperature luminescence of the [Ru(bpy)(tpy)]2+ core?. Chemical Communications, 2012, 48 (5), pp.741-3. ⟨10.1039/c1cc15737j⟩. ⟨hal-00832349⟩