Programmable multimetallic linear nanoassemblies of ruthenium-DNA conjugates

Joris Irvoas (1) , Arielle Noirot (1) , Nadia Chouini-Lalanne (1) , Olivier Reynes (2) , Jean-Christophe Garrigues (1) , Valérie Sartor (1)

1 IMRCP - Interactions moléculaires et réactivité chimique et photochimique
2 LGC - Laboratoire de Génie Chimique

A new ruthenium-DNA conjugates family was synthesized, made up of a ruthenium complex bound to one or two identical DNA strands of 14-58 nucleotides. The formation of controlled linear nanoassemblies containing one to seven ruthenium complexes is described.

Mots clés: DNA; Organic backbone; Ruthenium; Nanostructure

Domaines: Génie chimique

Joris Irvoas, Arielle Noirot, Nadia Chouini-Lalanne, Olivier Reynes, Jean-Christophe Garrigues, et al.. Programmable multimetallic linear nanoassemblies of ruthenium-DNA conjugates. RSC Advances, 2012, vol. 2, pp. 9538-9542. ⟨10.1039/c2ra21645k⟩. ⟨hal-00925042⟩