Is the 3MLCT the only photoreactive state of polypyridyl complexes?

Abstract : Characterization of metal-centered triplet states with two monodentate ligands in [Ru(bpy)3]2+ and [Ru(bpz)3]2+ complexes has been achieved by using the density functional theory method. These states are quasi-degenerate with their corresponding 3MLCT states and can readily react with their environment.
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Submitted on : Monday, February 3, 2014 - 1:03:57 PM
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Fabienne Alary, Jean-Louis Heully, L. Bijeire, Patricia Vicendo. Is the 3MLCT the only photoreactive state of polypyridyl complexes?. Inorganic Chemistry, American Chemical Society, 2007, 46 (8), pp.3154-3165. ⟨10.1021/ic062193i⟩. ⟨hal-00941075⟩

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