High-performance thermoplastic composites poly(ether ketone ketone)/silver nanowires: Morphological, mechanical and electrical properties

Luis Quiroga Cortes (1) , Antoine Lonjon (1) , Eric Dantras (1) , Colette Lacabanne (1)

1 CIRIMAT - Centre interuniversitaire de recherche et d'ingenierie des matériaux

High-performance conductive thermoplastic composites poly(ether ketone ketone) (PEKK)/silver nanowires were elaborated by melt blending. Silver nanowires (AgNWs) with high aspect ratio (ξ~220) were elaborated through the polyol process in presence of poly(vinyl pyrrolidone) (PVP) and ethylene glycol. Scanning electron microscopy observations of nanowires were performed after an adapted cleaning process. The dispersion of NWs in the polymeric matrixwas evaluated. A very lowpercolation threshold of 0.6 vol% was obtained. Electrical conductivity values obtained above the percolation threshold were among the highest measured for low-filled conductive polymer composites. The influence of AgNWs on the PEKK matrix has been investigated by differential scanning calorimetry and dynamic mechanical analyses. It is important to note that thermal and dynamic mechanical performances of the polymeric matrix were preserved in composites.

Mots clés: Nanowires; PEKK; Composites; Conductivity; Mechanical properties

Domaines: Polymères; Matériaux

Luis Quiroga Cortes, Antoine Lonjon, Eric Dantras, Colette Lacabanne. High-performance thermoplastic composites poly(ether ketone ketone)/silver nanowires: Morphological, mechanical and electrical properties. Journal of Non-Crystalline Solids, 2014, vol. 391, pp. 106-111. ⟨10.1016/j.jnoncrysol.2014.03.016⟩. ⟨hal-00976576⟩