Photo- and thermo-induced spin crossover in a cyanide-bridged {Mo(V)2Fe(II)2} rhombus molecule

Abhishake Mondal (1) , Yanling Li (1) , Lise-Marie Chamoreau (1) , Mannan Seuleiman (1) , Lionel Rechignat (2) , Azzedine Bousseksou (2) , Marie-Laure Boillot (3) , Rodrigue Lescouezec (1)

1 IPCM - Institut Parisien de Chimie Moléculaire
2 LCC - Laboratoire de chimie de coordination
3 ICMMO - Institut de Chimie Moléculaire et des Matériaux d'Orsay

The self-assembly of [Mo(V)(CN)8](3-) and [Fe(II)(bik)2(S)2](2+) affords a cyanide-bridged {Mo(V)2Fe(II)2} rhombus molecule that shows photomagnetic effect under laser light irradiation at low temperature and exhibits thermo-induced spin crossover near ambient temperature.

Domaines: Chimie de coordination

Abhishake Mondal, Yanling Li, Lise-Marie Chamoreau, Mannan Seuleiman, Lionel Rechignat, et al.. Photo- and thermo-induced spin crossover in a cyanide-bridged {Mo(V)2Fe(II)2} rhombus molecule. Chemical Communications, 2014, 50 (22), pp.2893-2895. ⟨10.1039/C3CC49164A⟩. ⟨hal-00992180⟩