Lattice dynamics in spin-crossover nanoparticles through nuclear inelastic scattering

Gautier Félix (1, 2) , Mirko Mikolasek (1, 2) , Haonan Peng (1) , William Nicolazzi (1) , Gábor Molnár (1) , Aleksandr I. Chumakov (3) , Lionel Salmon (1) , Azzedine Bousseksou (1)

1 LCC - Laboratoire de chimie de coordination
2 ICGM - Institut Charles Gerhardt Montpellier - Institut de Chimie Moléculaire et des Matériaux de Montpellier
3 ESRF - European Synchrotron Radiation Facility

We used nuclear inelastic scattering (NIS) to investigate the lattice dynamics in [Fe(pyrazine)(Ni(CN)4)] spin crossover nanoparticles. The vibrational density of states of iron was extracted from the NIS data, which allowed to determine characteristic thermodynamical and lattice dynamical parameters as well as their spin-state dependence. The optical part of the NIS spectra compares well with the Raman scattering data reflecting the expansion/contraction of the coordination octahedron during the spin transition. From the acoustic part, we extracted the sound velocity in the low-spin (vLS=2073±31m/s) and high-spin (vHS=1942±23m/s) states of the particles. The spin-state dependence of this parameter is of primary interest to rationalize the spin-transition behavior in solids as well as its dynamics and finite size effects.

Domaines: Science des matériaux [cond-mat.mtrl-sci]; Matériaux

Gautier Félix, Mirko Mikolasek, Haonan Peng, William Nicolazzi, Gábor Molnár, et al.. Lattice dynamics in spin-crossover nanoparticles through nuclear inelastic scattering. Physical Review B: Condensed Matter and Materials Physics (1998-2015), 2015, 91 (2), pp.024422. ⟨10.1103/PhysRevB.91.024422⟩. ⟨hal-01203694⟩