Atypical Stoichiometry for a 3D Bimetallic Oxalate- Based Long-range Ordered Magnet Exhibiting High Proton Conductivity
Résumé
The reproducible formation of a 3D oxalate based coordination compound of formula (NH4)5[MnII2CrIII3(ox)9]·10H2O, with an unusual MnII/CrIII ratio, is presented. The original topology of the anionic network leads to antiferromagnetic long-range ordering whereas its guests favour high humidity-dependent proton conductivity.
Origine : Fichiers produits par l'(les) auteur(s)