Stable (aryl)(phosphino)carbenes: New ligands for transition metals

E. Despagnet , Karinne Miqueu (1) , Heinz Gornitzka (2) , P.W. Dyer (3) , D. Bourissou (2) , G. Bertrand

1 IPREM - Institut des sciences analytiques et de physico-chimie pour l'environnement et les materiaux
2 LHFA - Laboratoire Hétérochimie Fondamentale et Appliquée
3 DEPARTMENT OF CHEMISTRY

The first direct complexation of a stable phosphino carbene to a transition metal center is described. Both η1- and η2-coordination modes have been characterized spectroscopically. The Fischer-type structure of the η1-carbene rhodium complex was revealed by an X-ray diffraction study. Copyright © 2002 American Chemical Society.

Domaines: Catalyse; Chimie de coordination; Chimie organique; Polymères; Chimie théorique et/ou physique

E. Despagnet, Karinne Miqueu, Heinz Gornitzka, P.W. Dyer, D. Bourissou, et al.. Stable (aryl)(phosphino)carbenes: New ligands for transition metals. Journal of the American Chemical Society, 2002, 124 (40), pp.11834-11835. ⟨10.1021/ja027201i⟩. ⟨hal-01613271⟩