Hybrid systems with Ag nanocrystals and Si nanostructures synthesized by ultra-low-energy ion beam synthesis

Marzia Carrada (1) , Assia Haj Salem (1) , Béatrice Pécassou (2) , Robert Carles (1) , Gérard Benassayag (3)

1 CEMES-NeO - Nano-Optique et Nanomatériaux pour l'optique
2 CEMES - Centre d'élaboration de matériaux et d'études structurales
3 CEMES-MEM - Matériaux et dispositifs pour l'Electronique et le Magnétisme

Hybrid systems based on silicon and silver nanocrystals (Si-NCs and Ag-NCs) are of considerable interest in photon conversion solar cells. Due to their plasmonic properties, Ag-NCs strongly increase the photoluminescence emission intensity of Si-NCs located in their vicinity, allowing, in principle, to solve the problem of their low emission yield. In this work, we have elaborated 2D networks of Ag-NCs and amorphous Si nanoparticles in a controlled way by using Ultra-Low-Energy Ion-Beam-Synthesis. In the proposed synthesis scheme, a 2D layer of Si-NCs is first obtained by implanting Si+ ions at ultra low energy (from 1 to 3 keV) in a SiO2 layer with subsequent high temperature thermal annealing. Then, Ag+ ions are implanted in the same matrix at energies between 3 and 10 keV and crystalline Ag-NCs are formed during the implantation step. Several configurations with either 2D arrays or a large band of Ag-NCs have been obtained following the Ag+ implantation energy. Enhancement of the PL emission from Si nanostructures, which is related to the presence of Ag-NCs, has been observed under specific arrangement of the two embedded subsystems. In this type of synthesis, a combination of physical phenomena including ion mixing, implantation damage, point defect, and thermal diffusion has been taken into account in order to explain and thus control the structural and the optical characteristics of the system.

Domaines: Science des matériaux [cond-mat.mtrl-sci]

Marzia Carrada, Assia Haj Salem, Béatrice Pécassou, Robert Carles, Gérard Benassayag. Hybrid systems with Ag nanocrystals and Si nanostructures synthesized by ultra-low-energy ion beam synthesis. Journal of Applied Physics, 2017, 122 (10), pp.103101. ⟨10.1063/1.5000360⟩. ⟨hal-01755324⟩