Determination of magnetic anisotropy in the LnTRENSAL complexes (Ln = Tb, Dy, Er) by Torque magnetometry

M. Perfetti (1) , E. Lucaccini (1) , L. Sorace (1) , Jean- Pierre Costes (2) , R. Sessoli (1)

1 Dipartimento di Chimica "U. Schiff" and UdR INSTM
2 LCC - Laboratoire de chimie de coordination

We report here a study about the magnetic anisotropy of the LnTRENSAL complexes (Ln = Tb, Dy, Er) performed by using cantilever torque magnetometry and electron paramagnetic resonance. For all of the compounds, we extracted a set of crystal-field parameters to obtain the energy-level splitting of the ground-state multiplet.

Domaines: Chimie de coordination

M. Perfetti, E. Lucaccini, L. Sorace, Jean- Pierre Costes, R. Sessoli. Determination of magnetic anisotropy in the LnTRENSAL complexes (Ln = Tb, Dy, Er) by Torque magnetometry. Inorganic Chemistry, 2015, 54 (7), pp.3090-3092. ⟨10.1021/acs.inorgchem.5b00288⟩. ⟨hal-01923972⟩