Platinum-catalysed intermolecular addition of carbonyl compounds to 1,6-enynes: Investigation of a new reaction pathway

Kévin Fourmy (1, 2) , M. El Louz (1, 2) , Sonia Mallet-Ladeira (3, 1) , Jean-Claude Daran (1) , Odile Dechy-Cabaret (1, 2) , Maryse Gouygou (1, 2)

1 LCC - Laboratoire de chimie de coordination
2 Toulouse INP - Institut National Polytechnique (Toulouse)
3 ICT - Institut de Chimie de Toulouse

A novel intermolecular addition of aldehydes to 1,6-enynes via a Pt-carbene intermediate provides the diastereoselective formation of valuable tricyclic compounds.

Domaines: Chimie de coordination

Kévin Fourmy, M. El Louz, Sonia Mallet-Ladeira, Jean-Claude Daran, Odile Dechy-Cabaret, et al.. Platinum-catalysed intermolecular addition of carbonyl compounds to 1,6-enynes: Investigation of a new reaction pathway. Dalton Transactions, 2016, 45 (34), pp.13294-13299. ⟨10.1039/c6dt01725h⟩. ⟨hal-01927693⟩