Group 6 transition-metal/boron frustrated Lewis pair templates activate N2 and allow its facile borylation and silylation
Résumé
The reaction of trans‐[M(N2)2(dppe)2] (M=Mo, 1Mo, M=W, 1W) with B(C6F5)3 (2) provides the adducts [(dppe)2M=N=N‐B(C6F5)3] (3) which can be regarded as M/B transition‐metal frustrated Lewis pair (TMFLP) templates activating dinitrogen. Easy borylation and silylation of the activated dinitrogen ligands in complexes 3 with a hydroborane and hydrosilane occur by splitting of the B−H and Si−H bonds between the N2 moiety and the perfluoroaryl borane. This reactivity of 3 is reminiscent of conventional frustrated Lewis pair chemistry and constitutes an unprecedented approach for the functionalization of dinitrogen.
Domaines
Chimie de coordination
Origine : Fichiers produits par l'(les) auteur(s)
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