Synthesis and characterization of first row metal complexes derived from a pyridinophane ligand functionalized by fluoroalcohol

Pascal Guillo (1, 2) , Jean-Claude Daran (1) , E. Manoury (1) , Rinaldo Poli (1, 3)

1 LCC - Laboratoire de chimie de coordination
2 IUT 'A' - Département de Chimie [Castres]
3 IUF - Institut universitaire de France

A new tetradentate N-donor ligand (L) based on 2,11-diaza[3.3](2,6)pyridinophane with N-bonded (CF3)(2)(OH)CCH2 groups is presented, along with the coordination compounds [(L)FeCl2][FeCl4], [(L)MnCl2], [(L)Cu(OAc)(2)] and [(L)Zn(OTf)(H2O)](OTf) (OAc=acetate; OTf=trifluomethylsulfonate). All metal complexes possess a distorted octahedral geometry around the metal center.

Domaines: Chimie de coordination

Pascal Guillo, Jean-Claude Daran, E. Manoury, Rinaldo Poli. Synthesis and characterization of first row metal complexes derived from a pyridinophane ligand functionalized by fluoroalcohol. ChemistrySelect, 2017, 2 (8), pp.2574-2577. ⟨10.1002/slct.201700404⟩. ⟨hal-01940167⟩