Synthesis of dissymmetric phosphorus dendrimers using an unusual protecting group

Evgeny K. Apartsin (1) , Alya G. Venyaminova (1) , Serge Mignani (2, 3, 4) , A.-M. Caminade (5) , Jean Pierre Majoral (5)

1 ICBFM SB RAS - Institute of Chemical Biology and Fundamental Medicine [Novosibirsk, Russia]
2 LCBPT - UMR 8601 - Laboratoire de Chimie et de Biochimie Pharmacologiques et Toxicologiques
3 UPD5 - Université Paris Descartes - Paris 5
4 USPC - Université Sorbonne Paris Cité
5 LCC - Laboratoire de chimie de coordination

The presence of an azido group directly linked to phosphorus functionalized monomeric species allows the synthesis of neutral or polycationic original phosphorus dendrimers of reduced symmetry bearing branches of different generations on the core.

Domaines: Chimie de coordination

Evgeny K. Apartsin, Alya G. Venyaminova, Serge Mignani, A.-M. Caminade, Jean Pierre Majoral. Synthesis of dissymmetric phosphorus dendrimers using an unusual protecting group. New Journal of Chemistry, 2018, 42 (11), pp.8985-8991. ⟨10.1039/C8NJ01229F⟩. ⟨hal-01957984⟩