Highly π electron-rich macro-aromatics: bis(p-aminophenyl)-carbo-benzenes and their DBA acyclic references

Arnaud Rives (1) , Iaroslav Baglai (1, 2) , Volodymyr Malytskyi (1, 2) , Valérie Maraval (1) , Nathalie Saffon-Merceron (3) , Zoia Voitenko (2) , Rémi Chauvin (1)

1 LCC - Laboratoire de chimie de coordination
2 Taras Shevchenko National University of Kyiv
3 ICT - Institut de Chimie de Toulouse

A series of stable quadrupolar bis(p-aminophenyl)-carbo-benzenes, featuring both donor–donor–donor p-frustration and central macro-aromaticity, is described and compared to the acyclic dibutatrienylacetylene (DBA) reference series.

Domaines: Chimie organique; Matériaux; Chimie théorique et/ou physique

Arnaud Rives, Iaroslav Baglai, Volodymyr Malytskyi, Valérie Maraval, Nathalie Saffon-Merceron, et al.. Highly π electron-rich macro-aromatics: bis(p-aminophenyl)-carbo-benzenes and their DBA acyclic references. Chemical Communications, 2012, 48 (70), pp.8763. ⟨10.1039/C2CC34176J⟩. ⟨hal-01965636⟩