Multifunctional redox polymers: Electrochrome, polyelectrolyte, sensor, electrode modifier, nanoparticle stabilizer, and catalyst template

C. Deraedt (1) , A. Rapakousiou (1) , Y. Wang (1) , L. Salmon (2) , M. Bousquet (3) , Dominique Astruc (1)

1 ISM - Institut des Sciences Moléculaires
2 LCC - Laboratoire de chimie de coordination
3 LCPO - Laboratoire de Chimie des Polymères Organiques

Simple “click” polycondensation metallopolymers of redox-robust bis(ethynyl)biferrocene (biFc) and di(azido) poly(ethylene glycol) (PEG400 and PEG1000) were designed for multiple functions including improvement of water solubility and biocompatibility, the introduction of mixed valency and sensing capabilities, and as nanoparticle stabilizers for catalysis.

Domaines: Chimie de coordination

C. Deraedt, A. Rapakousiou, Y. Wang, L. Salmon, M. Bousquet, et al.. Multifunctional redox polymers: Electrochrome, polyelectrolyte, sensor, electrode modifier, nanoparticle stabilizer, and catalyst template. Angewandte Chemie International Edition, 2014, 53 (32), pp.8445-8449. ⟨10.1002/anie.201403062⟩. ⟨hal-02007954⟩