Dispersion of graphite flakes into boehmite sols for the preparation of bi-layer-graphene / alumina coatings on stainless steel for tribological applications

Karim Hentour (1, 2) , Viviane Turq (1) , Alicia Weibel (1) , Florence Ansart (1) , Jean-Michel Sobrino (2) , Julien Garcia (2) , Pierre-François Cardey (2) , Christophe Laurent (1)

1 CIRIMAT - Centre interuniversitaire de recherche et d'ingenierie des matériaux
2 CEntre Technique des Industries Mécaniques - Cetim (FRANCE)

Carbon-alumina coatings on stainless steel were prepared by a sol-gel route. The dispersion of the commercial graphite flakes by an ultrasonic bath, an ultrasonic probe and a high-shear mixer, produce thinner flakes, fewlayered-graphene and bi-layer-graphene (BLG), respectively. The coatings were examined by optical and electron microscopy, interferential rugosimetry, optical profilometry and Raman spectroscopy. The friction coefficient against a steel ball is decreased by a factor of 5–7 and the wear volume is reduced by a factor of 6–38 compared to a pure alumina coating. The best results correspond to the sample prepared using the high-shear mixer. Delamination of the graphite flakes into BLG during the friction test provides the system with debris suitable for tribofilm building up and lubrication but it is better to already have carbon dispersed as BLG in the coating before the test, notably because the carbon surface area available is much higher.

Mots clés: Graphite; Graphene; Alumina; Composite coatings; Tribology

Domaines: Matériaux

Karim Hentour, Viviane Turq, Alicia Weibel, Florence Ansart, Jean-Michel Sobrino, et al.. Dispersion of graphite flakes into boehmite sols for the preparation of bi-layer-graphene / alumina coatings on stainless steel for tribological applications. Journal of the European Ceramic Society, 2019, 39 (4), pp.1304-1315. ⟨10.1016/j.jeurceramsoc.2018.10.027⟩. ⟨hal-02135665⟩