Polarization of electron-beam irradiated LDPE films: contribution to charge generation and transport
Résumé
Electron-beam irradiation is an alternative way to generate charges in insulating materials, at controlled position and quantity, in order to monitor their behaviour as regard transport phenomena under the space charge induced electric field or external field applied. In this study, Low Density Polyethylene (LDPE) films were irradiated by a 80 keV electron-beam with a flux of 1nA/cm 2 during 10 minutes in an irradiation chamber under vacuum conditions, and were then characterized outside the chamber using three experimental methods. The electrical behaviour of the irradiated material was assessed by space charge measurements using the Pulsed Electro-Acoustic (PEA) method under dc stress. The influence of the applied electric field polarity and amplitude has been tested in order to better understand the charge behaviour after electron-beam irradiation. Fourier Transform Infra-Red spectroscopy (FTIR) and Photoluminescence (PL) measurements were performed to evaluate the impact of the electron beam irradiation, i.e. deposited charges and energy, on the chemical structure of the irradiated samples. The present results show that the electrical behaviour in LDPE after irradiation is mostly driven by charges, i.e. by physical processes function of the electric field, and that changes in the chemical structure seems to be mild.
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