Growth and density control of nanometric nickel–iron cyanide-bridged objects on functionalized Si(100) surface

Simon Tricard (1) , Benoît Fleury (1) , Florence Volatron (1) , Claire Costa-Coquelard (1) , Sandra Mazerat (1) , Vincent Huc (1) , Christophe David (2) , Francois Brisset (1) , Frederic Miserque (3) , Pascale Jégou (4) , Serge Palacin (4) , Talal Mallah (1)

1 LPCNO - Laboratoire de physique et chimie des nano-objets
2 LPN - Laboratoire de photonique et de nanostructures
3 CEA - Commissariat à l'énergie atomique et aux énergies alternatives
4 LCSI - Laboratoire de Chimie des Surfaces et Interfaces

Isolated nanometric objects of the nickel–iron cyanide-bridged coordination network are obtained by a sequential growth on “molecular seeds” anchored on Si(100) surfaces. Control of the density and the size of the nano-objects is achieved by imposing a growth process without side nucleation.

Domaines: Chimie de coordination; Science des matériaux [cond-mat.mtrl-sci]; Chimie analytique; Catalyse; Matériaux; Polymères; Chimie-Physique [physics.chem-ph]

Simon Tricard, Benoît Fleury, Florence Volatron, Claire Costa-Coquelard, Sandra Mazerat, et al.. Growth and density control of nanometric nickel–iron cyanide-bridged objects on functionalized Si(100) surface. Chemical Communications, 2010, 46 (24), pp.4327. ⟨10.1039/c003039b⟩. ⟨hal-02403359⟩