Copper complexes of phosphorus dendrimers and their properties

Omar Alami (1, 2) , Regis Laurent (1) , Jean Pierre Majoral (1) , Nabil El brahmi (2) , Said El Kazzouli (2) , Anne-Marie Caminade (1)

1 LCC - Laboratoire de chimie de coordination
2 UEMF - Université Euro Méditerranéenne de Fès

Phosphorus dendrimers are highly branched macromolecules, built with one phosphorus atom at each branching point. These dendrimers can be functionalized at will on the terminal functions. Grafting as terminal functions ligands suitable for the complexation of copper has been carried out several times, in particular with the aim of using the corresponding complexes as catalysts in a range of reactions, from O-and N-arylations and-vinylations, to the asymmetric benzoylation of linear or cyclic diols. A sequel of this work concerns the study of anticancer activity of analogous dendritic copper complexes.

Mots clés: Dendrimers; Phosphorus; Copper complexes; Pyridine imine; Diketone; Catalysis

Domaines: Chimie de coordination

Omar Alami, Regis Laurent, Jean Pierre Majoral, Nabil El brahmi, Said El Kazzouli, et al.. Copper complexes of phosphorus dendrimers and their properties. Inorganica Chimica Acta Reviews, 2021, 517, pp.120212. ⟨10.1016/j.ica.2020.120212⟩. ⟨hal-03131594⟩